{"name":"sig","uri":"https://mofpp.ramabile.casa/net/sig","type":"net","published":true,"provenance":{"source":"rcsr+mofplus","source_id":"sig","retrieved":"2026-09-09T00:14:35.623812","licence_source":"MOF++ project decision, CONTEXT §6 (Licensing): MOF+ is this group's own service, so nets retrieved from it are the project's own data to license, and the project licenses its data CC BY 4.0. No third-party grant is claimed.","source_citation":{"source":"RCSR","name":"Reticular Chemistry Structure Resource","cite":"M. O'Keeffe, M. A. Peskov, S. J. Ramsden and O. M. Yaghi, 'The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets', Acc. Chem. Res. 2008, 41, 1782-1789","doi":"10.1021/ar800124u","url":"https://rcsr.anu.edu.au","copyright":"© 2019 RCSR.net","per_net_reference":null,"per_net_reference_note":"RCSR publishes a primary reference per net, but the Systre archive distributed as RCSRnets-2019-06-01.arc carries an empty 'ref' field in all 2930 records. The citation shown is for the RCSR resource as a whole, not for this net specifically."},"field_sources":{"catenated":"mofplus:name-heuristic","cella":"mofplus","cellalpha":"mofplus","cellb":"mofplus","cellbeta":"mofplus","cellc":"mofplus","cellgamma":"mofplus","cs":"mofplus","edges":"mofplus","natoms":"mofplus","rcsr_index":"rcsr","rcsr_index_provenance":"rcsr","source_id":"rcsr+mofplus","systre_key":"rcsr","systre_key_checksum":"rcsr","vertices":"mofplus","vs":"mofplus","vs_corroboration":"NOT checked. A vertex symbol names the shortest ring at each angle of a vertex; no ring perception is implemented in this project, so nothing here reproduces, compares or contradicts one, and every vertex symbol on this record is carried on the word of the source alone. Two properties of the string itself were checked: that it names one ring per angle, of which a d-coordinated vertex has d*(d-1)/2, and that it names a ring at all. Neither is a check on the rings, and a symbol that passes both can still be wrong.","licence":"mofpp-project-decision (CONTEXT §6)","topofile":"mofplus","retrieved_utc":"2026-09-09T00:14:35.623812+00:00","name_match":"uncorroborable","cs_corroboration":"checked: one walk over the net's own periodic topology per vertex class, matched against the sequences the source supplied (0 class(es) disagreed). The coordination sequences are the source's own, byte for byte. Only the question of which vertex class each one describes was settled here, by walking the periodic net from one atom of each class (services.topology.coordination_sequence) and matching that walk against the sequences the source supplied. No sequence was computed into the record, extended, repaired, or replaced by a walked one; a supplied sequence that matches no class is withheld, not corrected."}},"ordering":{"rcsr_index":1739,"rcsr_index_provenance":"derived","rcsr_index_absence":null,"rcsr_index_note":"Derived by this site, not published by RCSR: the 1-based position of the symbol in the ascending ASCII-lexicographic ordering of the 2930 symbols in the RCSR Systre archive of 2019-06-01. RCSR does not number its nets; this is our ordering of their symbols and nothing more.","complexity_rank":2298,"complexity_basis":{"level":3,"level_name":"cell_contents","fields":{"natoms":172,"edge_count":344},"tie_break":{"symbol":"sig"},"key":[3,172,344,"sig"],"unkeyed":false}},"spacegroup":null,"spacegroup_number":null,"transitivity":{"p":null,"q":null,"r":null,"s":null},"cell":[8.2685,8.2685,4.3572,90.0,90.0,90.0],"natoms":172,"catenated":false,"catenated_note":"No, on the MOF+ name heuristic: that source marks a catenated net by a -c in its name, which the legacy client filters on, and this is that marker read back. A name heuristic, not a computed property of the topology, and not a measurement either source made.","licence":"CC-BY-4.0","coordination_sequences":{"state":"corroborated","note":"The mapping of coordination sequences onto vertex classes that the source supplied was checked against a walk over the periodic topology of the net itself, one walk per vertex class, and agreed. The sequences are the values the source supplied; the walk settled nothing but which class each one describes.","provenance":"mofplus","corroboration":"checked: one walk over the net's own periodic topology per vertex class, matched against the sequences the source supplied (0 class(es) disagreed). The coordination sequences are the source's own, byte for byte. Only the question of which vertex class each one describes was settled here, by walking the periodic net from one atom of each class (services.topology.coordination_sequence) and matching that walk against the sequences the source supplied. No sequence was computed into the record, extended, repaired, or replaced by a walked one; a supplied sequence that matches no class is withheld, not corrected.","topology_mismatch":null,"class_mapping":null,"unresolved":null,"vertex_symbols":{"state":"unchecked","note":"The symbols below are the values the source supplied, and nothing corroborates them. The one check made here is on their shape — a d-coordinated vertex has d(d-1)/2 angles and a whole symbol names a ring at each — and no symbol below fails it. How many symbols that check could be applied to at all is served as shape_checked.","corroboration":"Not corroborated. The coordination sequences beside these symbols carry a corroboration of their own, stated under coordination_sequences; the vertex symbols carry none. A vertex symbol names the shortest ring at each angle of a vertex, no ring perception runs anywhere in this project, and so there is nothing here that could reproduce one: these strings are served on the word of the source alone. What was checked is their shape — a d-coordinated vertex has d(d-1)/2 angles and a whole symbol names a ring at each, and a string that lists fewer is flagged rather than served as a symbol. A string that passes that count can still be wrong in its rings, and nothing here says otherwise.","provenance":"mofplus","stored":172,"shape_checked":172,"truncated":[],"placeholder":[],"incomplete":[],"flagged":{},"absence_reason":"not recorded: no vertex symbol is stored for this vertex."}},"vertex_symbols":{"state":"unchecked","note":"The symbols below are the values the source supplied, and nothing corroborates them. The one check made here is on their shape — a d-coordinated vertex has d(d-1)/2 angles and a whole symbol names a ring at each — and no symbol below fails it. How many symbols that check could be applied to at all is served as shape_checked.","corroboration":"Not corroborated. The coordination sequences beside these symbols carry a corroboration of their own, stated under coordination_sequences; the vertex symbols carry none. A vertex symbol names the shortest ring at each angle of a vertex, no ring perception runs anywhere in this project, and so there is nothing here that could reproduce one: these strings are served on the word of the source alone. What was checked is their shape — a d-coordinated vertex has d(d-1)/2 angles and a whole symbol names a ring at each, and a string that lists fewer is flagged rather than served as a symbol. A string that passes that count can still be wrong in its rings, and nothing here says otherwise.","provenance":"mofplus","stored":172,"shape_checked":172,"truncated":[],"placeholder":[],"incomplete":[],"flagged":{},"absence_reason":"not recorded: no vertex symbol is stored for this vertex."},"systre":{"key":"3 1 2 0 0 0 1 3 0 0 0 1 4 0 0 0 1 5 0 0 0 2 6 0 0 0 2 7 0 0 0 2 8 0 0 0 3 9 0 0 0 3 10 0 0 0 3 11 0 0 0 4 12 0 0 0 4 13 0 0 0 4 14 0 0 0 5 15 0 0 0 5 16 0 0 0 5 17 0 0 0 6 9 0 0 0 6 18 0 0 0 6 19 0 0 0 7 12 0 0 0 7 20 0 0 0 7 21 0 0 0 8 15 0 0 0 8 22 0 0 0 8 23 0 0 0 9 24 0 0 0 9 25 0 0 0 10 13 0 0 0 10 23 1 0 0 10 26 0 0 0 11 17 0 0 0 11 27 0 0 0 11 28 0 0 0 12 29 0 0 0 12 30 0 0 0 13 31 0 0 0 13 32 0 0 0 14 16 0 0 0 14 33 0 0 0 14 34 0 0 0 15 26 -1 0 0 15 35 0 0 0 16 36 0 0 0 16 37 0 0 0 17 38 0 0 0 17 39 0 0 0 18 20 0 0 0 18 40 0 0 0 18 41 0 0 0 19 22 0 0 0 19 42 0 0 0 19 43 0 0 0 20 44 0 0 0 20 45 0 0 0 21 23 0 0 0 21 31 -1 0 0 21 46 0 0 0 22 47 0 0 0 22 48 0 0 0 23 24 -1 0 0 24 47 1 0 0 24 49 0 0 0 25 43 0 0 0 25 50 0 0 0 25 51 0 0 0 26 28 0 0 0 26 52 0 0 0 27 51 0 0 0 27 53 0 0 0 27 54 0 0 0 28 55 0 0 0 28 56 0 0 0 29 45 0 0 0 29 57 0 0 0 29 58 0 0 0 30 33 0 0 0 30 59 0 0 0 30 60 0 0 0 31 58 0 0 0 31 60 1 0 0 32 34 0 0 0 32 52 0 0 0 32 61 0 0 0 33 62 0 0 0 33 63 0 0 0 34 64 0 0 0 34 65 0 0 0 35 38 0 0 0 35 55 -1 0 0 35 66 0 0 0 36 52 -1 0 0 36 63 0 0 0 36 67 0 0 0 37 39 0 0 0 37 65 0 0 0 37 68 0 0 0 38 53 0 0 0 38 69 0 0 0 39 56 0 0 0 39 70 0 0 0 40 42 0 0 0 40 71 0 0 0 40 72 0 0 0 41 49 0 0 0 41 73 0 0 0 41 74 0 0 0 42 75 0 0 0 42 76 0 0 0 43 77 0 0 0 43 78 0 0 0 44 46 0 0 0 44 72 0 0 0 44 79 0 0 0 45 74 0 0 0 45 80 0 0 0 46 49 -1 0 0 46 81 0 0 0 47 50 -1 0 0 47 76 0 0 0 48 66 0 0 0 48 78 0 0 0 48 82 0 0 0 49 83 0 0 0 50 82 1 0 0 50 84 0 0 0 51 85 0 0 0 51 86 0 0 0 52 87 0 0 0 53 88 0 0 0 53 89 0 0 0 54 55 0 0 0 54 90 0 0 0 54 91 0 0 0 55 92 0 0 0 56 87 0 0 0 56 93 0 0 0 57 59 0 0 0 57 94 0 0 0 57 95 0 0 0 58 81 1 0 0 58 96 0 0 0 59 97 0 0 0 59 98 0 0 0 60 61 -1 0 0 60 99 0 0 0 61 63 1 0 0 61 100 0 0 0 62 64 0 0 0 62 98 0 0 0 62 101 0 0 0 63 102 0 0 0 64 100 0 0 0 64 103 0 0 0 65 87 0 0 0 65 104 0 0 0 66 88 0 0 0 66 90 -1 0 0 67 68 0 0 0 67 105 0 0 0 67 106 0 0 0 68 107 0 0 0 68 108 0 0 0 69 70 0 0 0 69 109 0 0 0 69 110 0 0 0 70 107 0 0 0 70 111 0 0 0 71 73 0 0 0 71 112 0 0 0 71 113 0 0 0 72 83 -1 0 0 72 114 0 0 0 73 115 0 0 0 73 116 0 0 0 74 81 1 0 0 74 117 0 0 0 75 77 0 0 0 75 113 0 0 0 75 118 0 0 0 76 83 -1 0 0 76 119 0 0 0 77 120 0 0 0 77 121 0 0 0 78 85 0 0 0 78 122 0 0 0 79 80 0 0 0 79 123 0 0 0 79 124 0 0 0 80 94 0 0 0 80 125 0 0 0 81 124 0 0 0 82 86 -1 0 0 82 126 0 0 0 83 116 0 0 0 84 119 1 0 0 84 120 0 0 0 84 127 0 0 0 85 88 0 0 0 85 128 0 0 0 86 90 0 0 0 86 129 0 0 0 87 105 1 0 0 88 130 0 0 0 89 91 0 0 0 89 109 0 0 0 89 125 0 1 0 90 131 0 0 0 91 132 0 0 0 91 133 0 0 0 92 93 0 0 0 92 110 1 0 0 92 133 0 0 0 93 111 0 0 0 93 134 0 0 0 94 109 0 -1 0 94 135 0 0 0 95 96 0 0 0 95 136 0 0 0 95 137 0 0 0 96 99 1 0 0 96 138 0 0 0 97 99 0 0 0 97 135 0 0 0 97 139 0 0 0 98 137 0 0 0 98 140 0 0 0 99 141 0 0 0 100 141 1 0 0 100 142 0 0 0 101 102 0 0 0 101 113 0 0 1 101 143 0 0 0 102 118 0 0 1 102 142 -1 0 0 103 113 0 0 1 103 120 0 0 1 103 144 0 0 0 104 108 0 0 0 104 120 0 0 1 104 145 0 0 0 105 134 -1 0 0 105 145 -1 0 0 106 118 0 0 1 106 121 0 0 1 106 127 -1 0 1 107 146 0 0 0 107 147 0 0 0 108 121 0 0 1 108 148 0 0 0 109 136 0 1 0 110 135 0 1 0 110 146 0 0 0 111 136 0 1 0 111 149 0 0 0 112 114 0 0 0 112 143 0 0 -1 112 150 0 0 0 114 151 0 0 0 114 152 0 0 0 115 150 0 0 0 115 153 0 0 0 115 154 0 0 0 116 144 0 0 -1 116 152 1 0 0 117 125 0 0 0 117 132 0 -1 0 117 154 0 0 0 118 119 0 0 0 119 144 -1 0 -1 121 122 0 0 0 122 126 0 0 0 122 155 0 0 0 123 130 0 -1 0 123 131 -1 -1 0 123 151 0 0 0 124 132 -1 -1 0 124 138 -1 0 0 125 130 0 -1 0 126 127 -1 0 0 126 156 0 0 0 127 145 0 0 -1 128 129 0 0 0 128 155 0 0 0 128 157 0 0 0 129 156 1 0 0 129 158 0 0 0 130 157 0 0 0 131 132 0 0 0 131 158 0 0 0 133 136 0 1 0 133 138 0 1 0 134 146 1 0 0 134 159 0 0 0 135 138 -1 0 0 137 141 1 0 0 137 160 0 0 0 139 140 0 0 0 139 161 0 0 0 139 162 0 0 0 140 143 0 0 0 140 163 0 0 0 141 162 0 0 0 142 144 0 0 0 142 164 0 0 0 143 164 -1 0 0 145 165 0 0 0 146 161 0 1 0 147 148 0 0 0 147 149 0 0 0 147 166 0 0 0 148 155 0 0 1 148 165 0 0 0 149 159 0 0 0 149 160 0 1 0 150 163 0 0 -1 150 167 0 0 0 151 167 0 0 0 151 168 0 0 0 152 153 -1 0 0 152 164 -1 0 -1 153 168 1 0 0 153 169 0 0 0 154 157 0 -1 0 154 158 0 -1 0 155 170 0 0 0 156 165 -1 0 -1 156 171 0 0 0 157 167 0 1 0 158 168 1 1 0 159 165 0 0 0 159 172 0 0 0 160 163 0 0 0 160 169 0 0 1 161 166 0 -1 0 161 172 -1 -1 0 162 164 -1 0 0 162 169 -1 0 1 163 166 0 -1 0 166 170 0 0 1 167 170 0 -1 0 168 171 0 -1 0 169 172 0 -1 -1 170 171 0 0 0 171 172 -1 0 -1","checksum":"dd4105d6189393fedc13bd2ef2474fb9","provenance":"rcsr","checksum_provenance":"rcsr","absence":null,"note":"The canonical Systre key, copied verbatim from the local RCSR Systre archive of 2019-06-01. It is not computed here and cannot be: no Gavrog/Systre toolchain runs on this machine, so nothing on this site derives, extends, repairs or verifies a key. The checksum served beside it is the one the archive itself carries, copied from the same block, so that this copy can be checked against the upstream file; no checksum is computed or verified 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