{"name":"tph-a","uri":"https://mofpp.ramabile.casa/net/tph-a","type":"net","published":true,"provenance":{"source":"rcsr+mofplus","source_id":"tph-a","retrieved":"2026-09-09T00:16:00.305926","licence_source":"MOF++ project decision, CONTEXT §6 (Licensing): MOF+ is this group's own service, so nets retrieved from it are the project's own data to license, and the project licenses its data CC BY 4.0. No third-party grant is claimed.","source_citation":{"source":"RCSR","name":"Reticular Chemistry Structure Resource","cite":"M. O'Keeffe, M. A. Peskov, S. J. Ramsden and O. M. Yaghi, 'The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets', Acc. Chem. Res. 2008, 41, 1782-1789","doi":"10.1021/ar800124u","url":"https://rcsr.anu.edu.au","copyright":"© 2019 RCSR.net","per_net_reference":null,"per_net_reference_note":"RCSR publishes a primary reference per net, but the Systre archive distributed as RCSRnets-2019-06-01.arc carries an empty 'ref' field in all 2930 records. The citation shown is for the RCSR resource as a whole, not for this net specifically."},"field_sources":{"catenated":"mofplus:name-heuristic","cella":"mofplus","cellalpha":"mofplus","cellb":"mofplus","cellbeta":"mofplus","cellc":"mofplus","cellgamma":"mofplus","cs":"mofplus","edges":"mofplus","natoms":"mofplus","rcsr_index":"rcsr","rcsr_index_provenance":"rcsr","source_id":"rcsr+mofplus","systre_key":"rcsr","systre_key_checksum":"rcsr","vertices":"mofplus","vs":"mofplus","vs_corroboration":"NOT checked. A vertex symbol names the shortest ring at each angle of a vertex; no ring perception is implemented in this project, so nothing here reproduces, compares or contradicts one, and every vertex symbol on this record is carried on the word of the source alone. Two properties of the string itself were checked: that it names one ring per angle, of which a d-coordinated vertex has d*(d-1)/2, and that it names a ring at all. Neither is a check on the rings, and a symbol that passes both can still be wrong.","licence":"mofpp-project-decision (CONTEXT §6)","topofile":"mofplus","retrieved_utc":"2026-09-09T00:16:00.305926+00:00","name_match":"uncorroborable","cs_corroboration":"checked: one walk over the net's own periodic topology per vertex class, matched against the sequences the source supplied (0 class(es) disagreed). The coordination sequences are the source's own, byte for byte. Only the question of which vertex class each one describes was settled here, by walking the periodic net from one atom of each class (services.topology.coordination_sequence) and matching that walk against the sequences the source supplied. No sequence was computed into the record, extended, repaired, or replaced by a walked one; a supplied sequence that matches no class is withheld, not corrected."}},"ordering":{"rcsr_index":2086,"rcsr_index_provenance":"derived","rcsr_index_absence":null,"rcsr_index_note":"Derived by this site, not published by RCSR: the 1-based position of the symbol in the ascending ASCII-lexicographic ordering of the 2930 symbols in the RCSR Systre archive of 2019-06-01. RCSR does not number its nets; this is our ordering of their symbols and nothing more.","complexity_rank":2339,"complexity_basis":{"level":3,"level_name":"cell_contents","fields":{"natoms":192,"edge_count":504},"tie_break":{"symbol":"tph-a"},"key":[3,192,504,"tph-a"],"unkeyed":false}},"spacegroup":null,"spacegroup_number":null,"transitivity":{"p":null,"q":null,"r":null,"s":null},"cell":[7.1663,7.1663,7.1663,90.0,90.0,90.0],"natoms":192,"catenated":false,"catenated_note":"No, on the MOF+ name heuristic: that source marks a catenated net by a -c in its name, which the legacy client filters on, and this is that marker read back. A name heuristic, not a computed property of the topology, and not a measurement either source made.","licence":"CC-BY-4.0","coordination_sequences":{"state":"corroborated","note":"The mapping of coordination sequences onto vertex classes that the source supplied was checked against a walk over the periodic topology of the net itself, one walk per vertex class, and agreed. The sequences are the values the source supplied; the walk settled nothing but which class each one describes.","provenance":"mofplus","corroboration":"checked: one walk over the net's own periodic topology per vertex class, matched against the sequences the source supplied (0 class(es) disagreed). The coordination sequences are the source's own, byte for byte. Only the question of which vertex class each one describes was settled here, by walking the periodic net from one atom of each class (services.topology.coordination_sequence) and matching that walk against the sequences the source supplied. No sequence was computed into the record, extended, repaired, or replaced by a walked one; a supplied sequence that matches no class is withheld, not corrected.","topology_mismatch":null,"class_mapping":null,"unresolved":null,"vertex_symbols":{"state":"unchecked","note":"The symbols below are the values the source supplied, and nothing corroborates them. The one check made here is on their shape — a d-coordinated vertex has d(d-1)/2 angles and a whole symbol names a ring at each — and no symbol below fails it. How many symbols that check could be applied to at all is served as shape_checked.","corroboration":"Not corroborated. The coordination sequences beside these symbols carry a corroboration of their own, stated under coordination_sequences; the vertex symbols carry none. A vertex symbol names the shortest ring at each angle of a vertex, no ring perception runs anywhere in this project, and so there is nothing here that could reproduce one: these strings are served on the word of the source alone. What was checked is their shape — a d-coordinated vertex has d(d-1)/2 angles and a whole symbol names a ring at each, and a string that lists fewer is flagged rather than served as a symbol. A string that passes that count can still be wrong in its rings, and nothing here says otherwise.","provenance":"mofplus","stored":192,"shape_checked":192,"truncated":[],"placeholder":[],"incomplete":[],"flagged":{},"absence_reason":"not recorded: no vertex symbol is stored for this vertex."}},"vertex_symbols":{"state":"unchecked","note":"The symbols below are the values the source supplied, and nothing corroborates them. The one check made here is on their shape — a d-coordinated vertex has d(d-1)/2 angles and a whole symbol names a ring at each — and no symbol below fails it. How many symbols that check could be applied to at all is served as shape_checked.","corroboration":"Not corroborated. The coordination sequences beside these symbols carry a corroboration of their own, stated under coordination_sequences; the vertex symbols carry none. A vertex symbol names the shortest ring at each angle of a vertex, no ring perception runs anywhere in this project, and so there is nothing here that could reproduce one: these strings are served on the word of the source alone. What was checked is their shape — a d-coordinated vertex has d(d-1)/2 angles and a whole symbol names a ring at each, and a string that lists fewer is flagged rather than served as a symbol. A string that passes that count can still be wrong in its rings, and nothing here says otherwise.","provenance":"mofplus","stored":192,"shape_checked":192,"truncated":[],"placeholder":[],"incomplete":[],"flagged":{},"absence_reason":"not recorded: no vertex symbol is stored for this vertex."},"systre":{"key":"3 1 2 0 0 0 1 3 0 0 0 1 4 0 0 0 1 5 0 0 0 1 6 0 0 0 1 7 0 0 0 2 3 0 0 0 2 4 0 0 0 2 8 0 0 0 2 9 0 0 0 2 10 0 0 0 3 6 0 0 0 3 9 0 0 0 3 11 0 0 0 4 7 0 0 0 4 10 0 0 0 4 12 0 0 0 5 13 0 0 0 5 14 0 0 0 5 15 0 0 0 5 16 0 0 0 6 7 0 0 0 6 9 0 0 0 6 17 0 0 0 7 9 0 0 0 7 10 0 0 0 7 18 0 0 0 8 19 0 0 0 8 20 0 0 0 8 21 0 0 0 8 22 0 0 0 9 10 0 0 0 9 23 0 0 0 10 24 0 0 0 11 25 0 0 0 11 26 0 0 0 11 27 0 0 0 11 28 0 0 0 12 29 0 0 0 12 30 0 0 0 12 31 0 0 0 12 32 0 0 0 13 14 0 0 0 13 15 0 0 0 13 33 0 0 0 13 34 0 0 0 14 16 0 0 0 14 34 0 0 0 14 35 0 0 0 15 16 0 0 0 15 34 0 0 0 15 36 0 0 0 16 34 0 0 0 16 37 0 0 0 17 38 0 0 0 17 39 0 0 0 17 40 0 0 0 17 41 0 0 0 18 42 0 0 0 18 43 0 0 0 18 44 0 0 0 18 45 0 0 0 19 20 0 0 0 19 21 0 0 0 19 46 0 0 0 19 47 0 0 0 20 22 0 0 0 20 47 0 0 0 20 48 0 0 0 21 22 0 0 0 21 47 0 0 0 21 49 0 0 0 22 47 0 0 0 22 50 0 0 0 23 51 0 0 0 23 52 0 0 0 23 53 0 0 0 23 54 0 0 0 24 55 0 0 0 24 56 0 0 0 24 57 0 0 0 24 58 0 0 0 25 26 0 0 0 25 27 0 0 0 25 59 0 0 0 25 60 0 0 0 26 28 0 0 0 26 60 0 0 0 26 61 0 0 0 27 28 0 0 0 27 60 0 0 0 27 62 0 0 0 28 60 0 0 0 28 63 0 0 0 29 30 0 0 0 29 31 0 0 0 29 64 0 0 0 29 65 0 0 0 30 32 0 0 0 30 65 0 0 0 30 66 0 0 0 31 32 0 0 0 31 65 0 0 0 31 67 0 0 0 32 65 0 0 0 32 68 0 0 0 33 49 0 0 0 33 64 0 0 0 33 69 0 0 0 33 70 0 0 0 34 71 0 0 0 35 62 0 0 0 35 72 0 0 0 35 73 0 0 0 35 74 0 0 0 35 75 0 0 0 36 59 1 0 0 36 67 0 0 0 36 76 0 0 0 36 77 0 0 0 37 50 0 1 0 37 78 0 0 0 37 79 0 0 0 37 80 0 0 0 37 81 0 0 0 38 39 0 0 0 38 40 0 0 0 38 74 0 0 0 38 82 0 0 0 39 41 0 0 0 39 70 0 0 1 39 82 0 0 0 40 41 0 0 0 40 78 0 0 0 40 82 0 0 0 41 76 0 0 1 41 82 0 0 0 42 43 0 0 0 42 44 0 0 0 42 83 0 0 0 42 84 0 0 0 43 45 0 0 0 43 73 1 -1 1 43 84 0 0 0 44 45 0 0 0 44 80 0 0 0 44 84 0 0 0 45 84 0 0 0 45 85 0 0 0 46 59 0 0 0 46 67 -1 0 0 46 85 -1 0 -1 46 86 0 0 0 47 75 0 -1 0 48 61 0 0 0 48 68 -1 0 0 48 87 0 0 0 48 88 0 0 0 49 64 0 0 0 49 69 0 0 0 49 89 0 0 0 49 90 0 0 0 50 66 0 0 0 50 78 0 -1 0 50 79 0 -1 0 50 91 0 0 0 51 52 0 0 0 51 53 0 0 0 51 88 0 0 0 51 92 0 0 0 52 54 0 0 0 52 77 0 -1 1 52 92 0 0 0 53 54 0 0 0 53 90 0 0 1 53 92 0 0 0 54 92 0 0 0 54 93 0 0 0 55 56 0 0 0 55 57 0 0 0 55 91 0 0 0 55 94 0 0 0 56 58 0 0 0 56 86 1 -1 1 56 94 0 0 0 57 58 0 0 0 57 94 0 0 0 57 95 0 0 0 58 72 1 -1 1 58 94 0 0 0 59 67 -1 0 0 59 77 -1 0 0 59 86 0 0 0 60 81 -1 0 0 61 68 -1 0 0 61 83 -1 0 0 61 88 0 0 0 62 72 0 0 0 62 74 0 0 0 62 93 -1 1 -1 62 96 0 0 0 63 69 0 0 1 63 70 0 0 1 63 89 0 0 1 63 90 0 0 1 64 70 0 0 0 64 90 0 0 0 65 96 1 -1 0 66 79 0 -1 0 66 81 0 -1 0 66 91 0 0 0 67 76 0 0 0 67 85 0 0 -1 68 83 0 0 0 68 87 1 0 0 68 95 0 0 0 69 70 0 0 0 69 89 0 0 0 69 94 -1 1 -1 70 90 0 0 0 71 83 -1 1 -1 71 87 0 1 -1 71 88 0 1 -1 71 95 -1 1 -1 72 73 0 0 0 72 93 -1 1 -1 73 75 0 0 0 73 93 -1 1 -1 73 96 0 0 0 74 75 0 0 0 74 96 0 0 0 75 96 0 0 0 76 77 0 0 0 76 85 0 0 -1 76 86 1 0 0 77 86 1 0 0 78 80 0 0 0 78 91 0 1 0 79 81 0 0 0 79 92 0 1 -1 80 81 0 0 0 80 91 0 1 0 81 91 0 1 0 82 87 0 1 0 83 88 1 0 0 83 95 0 0 0 84 89 1 0 1 85 86 1 0 1 87 88 0 0 0 87 95 -1 0 0 89 90 0 0 0 93 96 1 -1 1","checksum":"8bb10e520c3814b21f8d50af6daa4ef9","provenance":"rcsr","checksum_provenance":"rcsr","absence":null,"note":"The canonical Systre key, copied verbatim from the local RCSR Systre archive of 2019-06-01. It is not computed here and cannot be: no Gavrog/Systre toolchain runs on this machine, so nothing on this site derives, extends, repairs or verifies a key. The checksum served beside it is the one the archive itself carries, copied from the same block, so that this copy can be checked against the upstream file; no checksum is computed or verified 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